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Fast-synthesis and catalytic property of heterogeneous Co-MOF catalysts for the epoxidation of α-pinene with air

New Journal of Chemistry, ISSN: 1369-9261, Vol: 44, Issue: 40, Page: 17413-17421
2020
  • 15
    Citations
  • 0
    Usage
  • 9
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    15
    • Citation Indexes
      15
  • Captures
    9

Article Description

In the past decades, many methods have been developed for synthesizing MOFs, including solvothermal synthesis, mechanical synthesis, electrochemical synthesis, and microwave synthesis. Based on the existing research, a method is proposed for synthesizing Co-MOF by rapidly rotating hydrothermal crystallization, which largely shortens the crystallization time of Co-MOF. When the rotation speed was 150 rpm, only 2 h of crystallization time was needed to synthesize Co-MOF-150-2 with high crystallinity and stability. The optimal Co-MOF-150-2 manifested remarkable activity and selectivity for the epoxidation of α-pinene under mild conditions. The catalytic conversion of α-pinene reached the highest over the Co-MOF-150-2 catalyst, in which the conversion of α-pinene was 99.5% and the yield of 2,3-epoxypinane was 95.7%. The Co-MOF materials synthesized by the rotary method also had excellent stability and highly catalytic activity in recycling experiments. This journal is

Bibliographic Details

Haifu Zhang; Jie He; Xinhuan Lu; Lu Yang; Chenlong Wang; Fanfan Yue; Dan Zhou; Qinghua Xia

Royal Society of Chemistry (RSC)

Chemical Engineering; Chemistry; Materials Science

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