Dibenzopleiadiene-embeded polyaromatics: Via [4 + 3] annulative decarbonylation/decarboxylation
Organic Chemistry Frontiers, ISSN: 2052-4129, Vol: 8, Issue: 3, Page: 522-530
2021
- 23Citations
- 19Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
A novel strategy is developed for the synthesis of dibenzopleiadiene-embedded polycyclic aromatic hydrocarbons from 1,8-naphthalic anhydride derivatives and cyclic diaryliodonium salts through a palladium-catalyzed cascade [4 + 3] decarbonylative/decarboxylative annulation. The mechanism of the reaction is proposed and the molecular structure, photophysical properties, and frontier molecular orbitals of diverse dibenzopleiadiene-embedded polyaromatics are elucidated by X-ray crystallography, UV-Vis and fluorescence spectroscopy, and DFT calculations.
Bibliographic Details
Royal Society of Chemistry (RSC)
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