Hierarchical self-assembly of discrete bis-[2]pseudorotaxane metallacycle with bis-pillar[5]arene via host-guest interactions and their redox-responsive behaviors
RSC Advances, ISSN: 2046-2069, Vol: 11, Issue: 2, Page: 1187-1193
2020
- 2Citations
- 2Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations2
- Citation Indexes2
- CrossRef2
- Captures2
- Readers2
Article Description
A discrete rhomboidal metallacycle R functionalized with bis-[2]pseudorotaxane of [Cu(phenanthroline)2]+ derivatives was successfully synthesized via coordination-driven self-assembly. Furthermore, the host-guest complexation of such a bis-[2]pseudorotaxane metallacycle with a bis-pillar[5]arene (bisP5) allowed for the formation of a new family of cross-linked supramolecular polymers R⊃(bisP5)2, which displayed interesting redox-responsive properties. By taking advantage of the substantial structural differences between the coordination geometries of [Cu(phenanthroline)2]+ and [Cu(phenanthroline)2]2+, the weight-average diffusion coefficients D of the supramolecular polymer were adjusted through changing the redox state of the Cu(i)/Cu(ii) complexes. This journal is
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85099358096&origin=inward; http://dx.doi.org/10.1039/d0ra09920a; http://www.ncbi.nlm.nih.gov/pubmed/35423686; https://xlink.rsc.org/?DOI=D0RA09920A; https://dx.doi.org/10.1039/d0ra09920a; https://pubs.rsc.org/en/content/articlelanding/2021/ra/d0ra09920a
Royal Society of Chemistry (RSC)
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