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Electrochemiluminescence of Ru(bpy)/thioacetamide and its application for the sensitive determination of hepatotoxic thioacetamide

Analyst, ISSN: 1364-5528, Vol: 146, Issue: 16, Page: 5198-5203
2021
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Article Description

Thioacetamide (TAA) is a well-known hepatotoxic substance, so it is important to determine its presence and content in food and environmental samples. Herein, we report a highly sensitive determination method for TAA based on the electrochemiluminescence (ECL) of tris(2,2′-bipyridyl)ruthenium(ii) (Ru(bpy)32+) for the first time by using TAA as a new coreactant for Ru(bpy)32+ ECL via an anodic route. The developed Ru(bpy)32+-TAA ECL system allows the determination of TAA with a good dynamic linear range and low limit of detection (LOD) of 0.1 μM to 1000 μM and 0.035 μM (3σ/m), respectively. In addition, the established ECL system can be applied to detect TAA in fruit juice and waste water samples with outstanding recoveries. This journal is

Bibliographic Details

Kitte, Shimeles Addisu; Bushira, Fuad Abduro; Li, Haijuan; Jin, Yongdong

Royal Society of Chemistry (RSC)

Chemistry; Biochemistry, Genetics and Molecular Biology; Environmental Science

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