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Unexpected aliovalent cation substitution between two NLO materials LiBaBi(SeO)Fand BaBi(SeO)FO

Chemical Communications, ISSN: 1364-548X, Vol: 57, Issue: 24, Page: 2982-2985
2021
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Article Description

One new combination, alkali-metal and alkaline earth-metal selenite fluoride, LiBaBi(SeO)F(LBBSF) and its analogue BaBi(SeO)FO(BBSF) were reported here for the first time. Unusual aliovalent cation substitution between them affected the layer thickness and made the bond strains of [SeO] enhanced, thereby inducing greater distortions and affecting the SHG efficiencies. This work may provide thoughts for exploring new NLO materials.

Bibliographic Details

Shi, Shuangshuang; Lin, Chensheng; Zhao, Dan; Luo, Min; Cao, Liling; Peng, Guang; Ye, Ning

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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