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Cross β-arylmethylation of alcohols catalysed by recyclable Ti-Pd alloys not requiring pre-activation

Chemical Communications, ISSN: 1364-548X, Vol: 57, Issue: 42, Page: 5139-5142
2021
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Article Description

Ti-Pd alloy catalysts were developed for the cross β-arylmethylation between arylmethylalcohols and different primary alcohols via a hydrogen autotransfer mechanism. The alloy catalysts could be reused multiple times without the need for pre-activation. Analysis of the reaction solution by inductively coupled plasma atomic absorption spectroscopy indicated that only a minimal amount of Ti and no Pd was leached from the catalyst.

Bibliographic Details

Utsunomiya, Masayoshi; Kondo, Ryota; Oshima, Toshinori; Safumi, Masatoshi; Suzuki, Takeyuki; Obora, Yasushi

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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