Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility
Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 8, Page: 1139-1142
2022
- 13Citations
- 12Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations13
- Citation Indexes13
- 13
- CrossRef6
- Captures12
- Readers12
- 12
Article Description
An octa-nuclear zinc (Zn8) cluster-based two-fold interpenetrated metal-organic framework (MOF) of [(CH3)2NH2]2[Zn8O3(FDC)6]·7DMF (denoted as Zn8-as; H2FDC = 9H-fluorene-2,7-dicarboxylic acid; DMF = N,N-dimethylformamide) was synthesized by the reaction of a hard base of a curved dicarboxylate ligand (H2FDC) with the borderline acid of Zn(ii) under solvothermal conditions. Zn8-as shows significant crystal volume shrinkage upon heating, yielding a solvate-free framework of [(CH3)2NH2]2[Zn8O3(FDC)6] (Zn8-de). Zn8-de displays gated adsorption for C2H2 and type-I adsorption for CO2, attributed to the framework flexibility and the different interactions between the gas molecules and the host framework.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85123758457&origin=inward; http://dx.doi.org/10.1039/d1cc05893b; http://www.ncbi.nlm.nih.gov/pubmed/34981084; https://xlink.rsc.org/?DOI=D1CC05893B; https://dx.doi.org/10.1039/d1cc05893b; https://pubs.rsc.org/en/content/articlelanding/2022/cc/d1cc05893b
Royal Society of Chemistry (RSC)
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