Hydride reduction of o-(fluorosilyl)benzodifluorides for subsequent C-F transformations
Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 21, Page: 3521-3524
2022
- 3Citations
- 4Captures
- 1Mentions
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吉田 優 Suguru Yoshida
吉田 優（よしだ すぐる）は、日本の化学者。専門は、有機合成化学、ケミカルバイオロジー。2022年現在、東京理科大学先進工学部生命システム工学科 准教授。第34回ケムステVシンポ「日本のクリックケミストリー」講師。O […]
Article Description
An efficient method for sequential C-F transformations of o-hydrosilyl-substituted benzotrifluorides is disclosed. A key to the success is hydride reduction of o-fluorosilyl-substituted difluoromethylenes prepared by a single C-F transformation of o-hydrosilyl-substituted benzotrifluorides. We succeeded in further C-F transformations via hydride abstraction of the resulting o-hydrosilyl group, enabling us to synthesize a wide variety of organofluorine compounds.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85126152619&origin=inward; http://dx.doi.org/10.1039/d1cc06761c; http://www.ncbi.nlm.nih.gov/pubmed/35195117; https://xlink.rsc.org/?DOI=D1CC06761C; https://dx.doi.org/10.1039/d1cc06761c; https://pubs.rsc.org/en/content/articlelanding/2022/cc/d1cc06761c
Royal Society of Chemistry (RSC)
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