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From ferrocene to 1,2,3,4,5-pentafluoroferrocene: Halogen effect on the properties of metallocene

Dalton Transactions, ISSN: 1477-9234, Vol: 50, Issue: 46, Page: 16933-16938
2021
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Article Description

The sequentially fluorinated ferrocenes (1-, 1,2-di, 1,2,3-tri, 1,2,3,4-tetra and 1,2,3,4,5-pentafluoroferrocene) have been synthesized from ferrocene. Rather than a 'perfluoro' effect, experimental and computational analysis of the complete series robustly demonstrates a linear additive effect of fluorine on the electrochemical and spectroscopic properties of ferrocene.

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