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Atom- and step-economic 1,3-thiosulfonylation of activated allenes with thiosulfonates to access vinyl sulfones/sulfides

Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 47, Page: 6765-6768
2022
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Article Description

A new type of organocatalyzed 1,3-thiosulfonylation has been developed to straightforwardly access highly functionalized vinyl sulfones, which features mild conditions, atom- and step-economy, practicability, conciseness, and environmental friendliness. Moreover, these valuable products can be transformed to vinyl sulfides via a base-promoted isomerization. The versatile route can efficiently and rapidly introduce SCD groups with excellent levels of deuterium content (>99% D) by utilizing our newly developed SCD reagents. Gram-scale operations and further transformations are smoothly carried out, providing promising applications for drug discovery.

Bibliographic Details

Xiao, Xiao; Tian, Hong-Yu; Huang, Yin-Qiu; Lu, Yin-Jie; Fang, Jing-Jie; Zhou, Gao-Jie; Chen, Fen-Er

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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