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Ion-pairing assemblies of heteroporphyrin-based π-electronic cation with various counteranions

Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 71, Page: 9870-9873
2022
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Article Description

Various counteranions of the thiaporphyrin-Ni complex as a π-electronic cation were exchanged for preparing stable ion pairs. The ion-pairing assembling modes, which included contributions of charge-by-charge and charge-segregated modes, and properties depended on the geometries and electronic states of the counteranions.

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