TEMPO coordination and reactivity in group 6; pseudo-pentagonal planar (η-TEMPO)CrX (X = Cl, TEMPO)
Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 70, Page: 9818-9821
2022
- 3Citations
- 5Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
The exposure of CrCl(THF) to 1 equiv. of TEMPO and 1 equiv. [TEMPO]Na afforded (η-O,N-TEMPO)CrCl (1, 67%); addition of [TEMPO]Na to 1 yielded (η-O,N-TEMPO)Cr(TEMPO) (2). Both 1 and 2 exhibit pseudo-pentagonal planar (PPP) geometry, instead of myriad alternatives. Calculations and spectral studies suggest the solid-state geometry persists in solution.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85136469868&origin=inward; http://dx.doi.org/10.1039/d2cc03838b; http://www.ncbi.nlm.nih.gov/pubmed/35975596; https://xlink.rsc.org/?DOI=D2CC03838B; https://dx.doi.org/10.1039/d2cc03838b; https://pubs.rsc.org/en/content/articlelanding/2022/cc/d2cc03838b
Royal Society of Chemistry (RSC)
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