Optical sensing of aqueous nitrate anion by a platinum(ii) triimine salt based solid state material
Chemical Communications, ISSN: 1364-548X, Vol: 58, Issue: 87, Page: 12160-12163
2022
- 2Citations
- 4Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Selective and quantitative measurement of aqueous nitrate (NO) anion is achieved using solid [Pt(Cl-4-tpy)Cl]ClO salt (Cl-4-tpy = 4-chloro-2,2′:6′2′′-terpyridine), and as the salt supported on controlled porous glass. This detection method relies on the color change of the Pt(ii) complex from yellow to red and intense luminescence response upon ClO exchange with NO due to concomitant enhancement of Pt⋯Pt interactions. The spectroscopic response is highly selective for NO over a large range of halides and oxoanions.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85140317653&origin=inward; http://dx.doi.org/10.1039/d2cc04732b; http://www.ncbi.nlm.nih.gov/pubmed/36200395; https://xlink.rsc.org/?DOI=D2CC04732B; https://dx.doi.org/10.1039/d2cc04732b; https://pubs.rsc.org/en/content/articlelanding/2022/cc/d2cc04732b
Royal Society of Chemistry (RSC)
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