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Formation of a meltable purinate metal-organic framework and its glass analogue

Chemical Communications, ISSN: 1364-548X, Vol: 59, Issue: 6, Page: 732-735
2022
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Article Description

The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name ZIF-UC-7. We find that it melts and forms a glass at one of the lowest temperatures reported for 3D hybrid frameworks.

Bibliographic Details

Bumstead, Alice M; Castillo-Blas, Celia; Pakamorė, Ignas; Thorne, Michael F; Sapnik, Adam F; Chester, Ashleigh M; Robertson, Georgina; Irving, Daniel J M; Chater, Philip A; Keen, David A; Forgan, Ross S; Bennett, Thomas D

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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