Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation
Chemical Communications, ISSN: 1364-548X, Vol: 59, Issue: 28, Page: 4193-4196
2023
- 1Citations
- 7Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
A series of (NHC)(cod)Ir(i) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(i) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85152173915&origin=inward; http://dx.doi.org/10.1039/d2cc06865f; http://www.ncbi.nlm.nih.gov/pubmed/36942515; https://xlink.rsc.org/?DOI=D2CC06865F; https://dx.doi.org/10.1039/d2cc06865f; https://pubs.rsc.org/en/content/articlelanding/2023/cc/d2cc06865f
Royal Society of Chemistry (RSC)
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