Aldolase and N-heterocyclic carbene gold(i) catalysts: compartmentalization and immobilization on anionic clays for concurrent hybrid catalysis at acidic pH
Catalysis Science and Technology, ISSN: 2044-4761, Vol: 13, Issue: 6, Page: 1623-1627
2023
- 6Citations
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Article Description
The last limitation to concurrent reactions involving hybrid catalysis, i.e. the pH, has been solved in a model hydration-aldolisation cascade towards a rare monosaccharide synthesis by mixing a NHC-gold catalyst and an aldolase. Through enzyme confinement in a cell, itself immobilised and catalysts compartmentalized, pH and catalyst incompatibilities were overcome, giving the corresponding aldol in 68% isolated yield, then opening the scope to other cascade reactions.
Bibliographic Details
Royal Society of Chemistry (RSC)
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