Bis(4-carboxylpyrazol-1-yl)acetic acid: a scorpionate ligand for complexes with improved water solubility
Dalton Transactions, ISSN: 1477-9234, Vol: 51, Issue: 17, Page: 6839-6845
2022
- 2Citations
- 5Captures
- 1Mentions
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Scorpionate Complexes with Improved Water Solubility
Bis(4-carboxylpyrazol-1-yl)acetic acid ligand prepared in one-pot process
Article Description
Bis(4-carboxylpyrazol-1-yl)acetic acid (Hbcpza) (2), obtained in a one-pot synthesis, contains carboxyl groups that differ in their pK values. The ligand exhibits heteroscorpionate κ-N,N,O-coordination whereupon the peripheral carboxyl groups are not involved in metal binding. The corresponding carbonyl complexes [Mn(Hbcpza)(CO)] (4), [Re(Hbcpza)(CO)] (5) and [Ru(Hbcpza)Cl(CO)] (6a/6b) are partially soluble in water but readily soluble in PBS buffer.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85129700115&origin=inward; http://dx.doi.org/10.1039/d2dt00848c; http://www.ncbi.nlm.nih.gov/pubmed/35438696; https://xlink.rsc.org/?DOI=D2DT00848C; https://dx.doi.org/10.1039/d2dt00848c; https://pubs.rsc.org/en/content/articlelanding/2022/dt/d2dt00848c
Royal Society of Chemistry (RSC)
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