A water-stable ZnO-based MOF decorated with carbazolyl chromophores for multi-responsive fluorescence sensing of Fe, CrO and nitro-compounds
New Journal of Chemistry, ISSN: 1369-9261, Vol: 46, Issue: 39, Page: 18710-18717
2022
- 10Citations
- 2Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
A novel luminescent isoreticular metal-organic framework ZnO(ECMTDC)·10DMF (Cz-MOF-1), where ECMTDC denotes 3-(9-ethyl-9H-carbazol-3-yl)-4-methylthieno[2,3-b]thiophene-2,5-dicarboxylate and DMF denotes N,N-dimethylformamide, was successfully synthesized via solvothermal methods from Zn(NO)·6HO and H2ECMTDC in DMF. Powder X-ray diffraction experiments along with scanning electron microscopy images indicate that Cz-MOF-1 has excellent water stability compared with other ZnO-based MOFs, which can be attributed to the hydrophobic surroundings around the ZnO clusters formed from N-ethylcarbazolyl and methyl groups. Cz-MOF-1 displays a strong deep blue light emission (452 nm) and a quantum efficiency of 3.74%, and has high selectivity and sensitivity for the detection of Fe, CrO and DCN. Furthermore, the possible luminescence sensing mechanisms have been discussed in detail, which are supported by PXRD analysis, UV-vis spectroscopy and density functional theory (DFT).
Bibliographic Details
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know