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Hydrosilylation and electroreduction of CO using a zirconocene hydride catalyst

New Journal of Chemistry, ISSN: 1369-9261, Vol: 47, Issue: 9, Page: 4504-4509
2023
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Article Description

A zirconium-based catalytic system using the commercially available complex [CpZrHCl] (Schwartz reagent) was developed for the hydrosilylation of CO to yield methanol via the formation of methoxy-silanes with excellent yields (>99%). Key mechanistic insights are also documented. In addition, electrochemical studies were carried out to determine its electro-reductive activity, and CO was identified as one of the CO reduction products.

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