A metal-free protocol for the preparation of amines using ammonia borane under mild conditions
Organic Chemistry Frontiers, ISSN: 2052-4129, Vol: 10, Issue: 4, Page: 970-976
2022
- 5Citations
- 2Captures
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Article Description
A mild and convenient reductive amination protocol for the synthesis of structurally diverse secondary and tertiary amines as well as N-methylated products under metal-free conditions is presented. This one-pot protocol works efficiently at room temperature using ammonia borane as the reductant and is applicable to a wide range of substrates, including chiral amines and amino acid derivatives. The synthetic utility and practicability of this methodology is demonstrated by gram-scale reactions and selected synthesis of current drug molecules.
Bibliographic Details
Royal Society of Chemistry (RSC)
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