A regio- and stereoselective Heck-Matsuda process for construction of γ-aryl allylsulfonyl fluorides
RSC Advances, ISSN: 2046-2069, Vol: 12, Issue: 30, Page: 19402-19405
2022
- 2Citations
- 4Captures
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Article Description
A highly efficient regio- and stereoselective Heck-Matsuda method was developed employing aryl diazoniums and allylsulfonyl fluorides for the construction of a class of novel γ-aryl allylsulfonyl fluorides in the presence of Pd(OAc) and PPh. The method features excellent regio- and stereoselectivity (up to 100% E-selectivity), broad substrate scope and mild reaction conditions. Further application of γ-aryl allylsulfonyl fluoride in SuFEx reactions was achieved to provide their corresponding sulfonates and sulfonamides in excellent yields.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85134310278&origin=inward; http://dx.doi.org/10.1039/d2ra03733e; http://www.ncbi.nlm.nih.gov/pubmed/35865583; https://xlink.rsc.org/?DOI=D2RA03733E; https://dx.doi.org/10.1039/d2ra03733e; https://pubs.rsc.org/en/content/articlelanding/2022/ra/d2ra03733e
Royal Society of Chemistry (RSC)
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