Cu(BTC) nanoflakes synthesized in an ionic liquid/water binary solvent and their catalytic properties
Soft Matter, ISSN: 1744-6848, Vol: 18, Issue: 32, Page: 6009-6014
2022
- 3Citations
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Article Description
Low-dimensional metal-organic frameworks (MOFs) exhibit enhanced properties compared with three-dimensional (3D) geometry MOFs in many fields. In this work, we demonstrate the synthesis of Cu(BTC) (BTC = benzene-1,3,5-tricarboxylate) nanoflakes in a binary solvent of ionic liquid (IL) and water. Such a MOF architecture has a high surface area and abundant unsaturated coordination metal sites, making them attractive for adsorption and catalysis. For example, in catalyzing the oxidation reactions of a series of alcohols, the Cu(BTC) nanoflakes exhibit a high performance that is superior to Cu(BTC) microparticles synthesized in a conventional solvent. Experimental and theoretical studies reveal that the IL accelerates the crystallization of Cu(BTC), while water plays a role in stripping the Cu(BTC) blocks that are formed at an early stage through its attack on the crystal plane of Cu(BTC). Such an in situ crystallization-exfoliation process that uses an IL/water solvent opens a new route for producing low-dimensional MOFs.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85135564896&origin=inward; http://dx.doi.org/10.1039/d2sm00749e; http://www.ncbi.nlm.nih.gov/pubmed/35920400; https://xlink.rsc.org/?DOI=D2SM00749E; https://dx.doi.org/10.1039/d2sm00749e; https://pubs.rsc.org/en/content/articlelanding/2022/sm/d2sm00749e
Royal Society of Chemistry (RSC)
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