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Photoinduced copper-catalyzed selective three-component 1,2-amino oxygenation of 1,3-dienes

Chemical Communications, ISSN: 1364-548X, Vol: 59, Issue: 69, Page: 10388-10391
2023
  • 13
    Citations
  • 0
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  • 4
    Captures
  • 0
    Mentions
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Metrics Details

  • Citations
    13
    • Citation Indexes
      13
  • Captures
    4

Article Description

This study presents a highly effective method for the photoinduced copper-catalyzed 1,2-amino oxygenation of 1,3-dienes. This synthetic strategy involves the dual roles of a single copper catalyst, which can act as a photosensitizer to generate nitrogen radicals and can also react with allyl radicals via single electron transfer (SET) processes. The method produces a range of quaternary carbon-centered allyl carboxylic esters and tertiary ethers with high yields and excellent regioselectivity under mild reaction conditions.

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