Construction of unsymmetrical heterobiaryls via the Cp*Rh(iii)-catalysed C-H/C-H coupling of heteroarenes
Chemical Communications, ISSN: 1364-548X, Vol: 59, Issue: 63, Page: 9646-9649
2023
- 10Citations
- 3Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
Herein, a concise method for the Rh(iii)-catalyzed, directing-group-assisted C-H/C-H cross-coupling of N-heterocycles (quinolines, indolines, indoles, pyridines, pyrimidines, pyrazoles) with other heteroarenes (benzoxazoles, benzofurans, and thiophenes) is disclosed for the synthesis of unsymmetrical heterobiaryl compounds in good to excellent yields. A plausible catalytic cycle has been delineated based on experimental and computational mechanistic studies.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85166268211&origin=inward; http://dx.doi.org/10.1039/d3cc03166g; http://www.ncbi.nlm.nih.gov/pubmed/37465886; https://xlink.rsc.org/?DOI=D3CC03166G; https://dx.doi.org/10.1039/d3cc03166g; https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc03166g
Royal Society of Chemistry (RSC)
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