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Photoinduced fluorescence modulation through controllable intramolecular [2+2] photocycloaddition in single molecules and molecular aggregates

Chemical Communications, ISSN: 1364-548X, Vol: 60, Issue: 10, Page: 1301-1304
2024
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Article Description

We report a general molecular design strategy of spatial proximity, which allows intramolecular [2+2] photocycloaddition reaction to take place in both single molecules and molecular aggregates. Sharply contrasting photoinduced fluorescence changes in solution and in the solid state were found and attributed to the aggregation-induced quenching property of the monomers and the aggregation-induced emission nature of the photodimers.

Bibliographic Details

Wu, Yuzhen; Ping, Xinni; Yao, Chuangye; Wu, Penglei; Han, Zhengdong; Peng, Xin; Zhan, Jiale; Feng, Hui; Qian, Zhaosheng

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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