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One-step synthesis of a ZIF-8/90-based type I porous liquid

Dalton Transactions, ISSN: 1477-9234, Vol: 52, Issue: 46, Page: 17213-17218
2023
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Article Description

A Type I porous liquid based on the mixed-linker zeolitic imidazolate framework, ZIF-8/90-PL, has been prepared by a one-step imine condensation reaction and characterized by X-ray diffraction, FT-IR spectroscopy, TGA and rheology analysis. This facile preparation strategy of a porous liquid has enormous industrial production and application potential, with over one kilogram of ZIF-8/90-PL being successfully prepared. ZIF-8/90-PL can be directly used as a liquid absorbent or be co-processed with alumina hollow fibers to form a composite membrane with improved selectivity in the context of CO separation from CH or N. This simple synthesis method is expected to be extended to other metal-organic frameworks.

Bibliographic Details

Hu, Jingqiu; Liu, Zhaofang; Tang, Shuangyin; Yao, Meng; Zhang, Dezhen; Cui, Mifen; Yang, Dong; Tang, Jihai; Qiao, Xu; Zhang, Zhuxiu

Royal Society of Chemistry (RSC)

Chemistry

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