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Stereoselective oxidative O-glycosylation of disarmed glycosyl iodides with alcohols using PIDA as the promoter

Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 21, Issue: 32, Page: 6479-6483
2023
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Article Description

The direct and practical oxidative anomeric O-glycosylation of glycosyl iodides with an array of alcohols as glycosyl acceptors is presented. Using phenyliodine(iii) diacetate (PIDA) as the promoter of the reaction, at ambient temperature, an enviromentally benign and operationally simple protocol has been developed providing access stereoselectively to 1,2-trans-O-glycosides.

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