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A surface-dynamic approach toward supercrystal engineering of titanium-oxo clusters

Inorganic Chemistry Frontiers, ISSN: 2052-1553, Vol: 10, Issue: 19, Page: 5694-5699
2023
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Article Description

The controlled synthesis and structure determination of two titanium-oxo (Ti-O) clusters (TiCu) (sp: hard-sphere-like packing) and (TiCu) (cs: chain stacking) are presented. In contrast to the previously reported assemblies of Ti-O clusters by organic or inorganic linkers, (TiCu) and (TiCu) are achieved via regulating the surface dynamics of Ti-O clusters and further stabilized by CH⋯π interactions. The surface dynamics was regulated via a change of dynamically detached Sal-Cu/OMe-Cu motifs (Sal = salicylic acid). More importantly, benefiting from the difference in structures, (TiCu) exhibits excellent conductive properties and different photocatalytic activities.

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