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Interfacial self-assembly of a chiral pyrene exciplex into a superhelix with enhanced circularly polarized luminescence

Chemical Communications, ISSN: 1364-548X, Vol: 60, Issue: 52, Page: 6631-6634
2024
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Article Description

We found that the interfacially confined self-assembly of pyrene and phenanthrene glutamides can form strong exciplexes and amorphous superhelices, which show intensity-enhanced and sign-inverted CPL activity with improved quantum yield compared to a pyrene excimer. This work unveils the predominant role of supramolecular nanostructures over molecular configurations on CPL performance.

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