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The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]

Chemical Communications, ISSN: 1364-548X, Vol: 60, Issue: 65, Page: 8621-8624
2024
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The tetracyanoborate anion [B(CN)] (TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN){CN-Cr(CO)}] (x = 1-4; 1-4) and [{Cr(CO)(B(CN))}] (5). The reaction of [B(CN)] with fac-[Cr(CO)(MeCN)] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)(B(CN))}]

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