The tetracyanoborate anion as a building block for the heterocubane cluster cage [Cr{B(CN)}]
Chemical Communications, ISSN: 1364-548X, Vol: 60, Issue: 65, Page: 8621-8624
2024
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Article Description
The tetracyanoborate anion [B(CN)] (TCB) was utilized as a building block for the synthesis of polynuclear chromium carbonyl compounds upon photolytic reaction with [Cr(CO)]. Up to four κN-coordinated cyano groups of TCB can be involved in binding to chromium, giving mixtures of [B(CN){CN-Cr(CO)}] (x = 1-4; 1-4) and [{Cr(CO)(B(CN))}] (5). The reaction of [B(CN)] with fac-[Cr(CO)(MeCN)] led to isolation of salts of the tetraanionic heterocubane cage [{Cr(CO)(B(CN))}]
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85199711571&origin=inward; http://dx.doi.org/10.1039/d4cc03022b; http://www.ncbi.nlm.nih.gov/pubmed/39046269; https://xlink.rsc.org/?DOI=D4CC03022B; https://dx.doi.org/10.1039/d4cc03022b; https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc03022b
Royal Society of Chemistry (RSC)
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