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Lifetime thermometry with an ytterbium(iii)-terbium(iii) molecular upconverter

Journal of Materials Chemistry C, ISSN: 2050-7534, Vol: 12, Issue: 38, Page: 15413-15417
2024
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Article Description

In this work, we report the first example of lifetime thermometry with a molecular upconverter. To reach our goal, we synthesized a {Tb10Yb10} molecular cluster-aggregate that emits via a cooperative upconversion mechanism. The operational temperature of the lifetime-based thermometer is in the 23-45 °C range with a maximum relative sensitivity of 2.26% °C at 45 °C.

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