Dimerization and solvation equilibria: the direct correlation function
Journal of Chemical Physics, ISSN: 0021-9606, Vol: 113, Issue: 9, Page: 3766-3771
2000
- 6Citations
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Article Description
In this study, Wertheim's methods were used to account for the solvation of a particle or alternatively the dimerization of two particles. For this purpose, a binary mixture of a and b particles that interact as hard spheres, and experience a short range, strong anisotropic attractive a, b interaction was considered. Results of this study not only comply with all the usual dictates of the Percus-Yevick (PY) approximation, but also satisfy symmetries derived from the exchange of particle labels.
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