PlumX Metrics
Embed PlumX Metrics

Solid state supercapacitor materials: Layered structures of yttria-stabilized zirconia sandwiched between platinum/yttria-stabilized zirconia composites

Journal of Applied Physics, ISSN: 0021-8979, Vol: 90, Issue: 10, Page: 5303-5307
2001
  • 17
    Citations
  • 0
    Usage
  • 19
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    17
    • Citation Indexes
      17
  • Captures
    19

Article Description

Layered structures of cubic yttria-stabilized zirconia (YSZ) sandwiched between two layers of platinum/YSZ composites with the platinum concentration varying between 20 and 55 vol % were prepared. Large double-layer capacitances were obtained due to the presence of large three-dimensional electrode surface areas in the composite layers. The layers were subjected to image analysis obtained from scanning electron microscopy micrographs. The specific surface area of the platinum particles decreased from ∼ 17 × 10 to ∼ 13.5 × 10 cm/cm with increasing Pt concentration. Image analyses obtained with an in-lens detector revealed that the effective surface area of the Pt particles that were part of a conducting percolative network increased with Pt concentration to ca. 11 × 10 cm/cm at a Pt metal volume fraction of 0.50. Impedance spectroscopy measurements performed at 550°C demonstrated that the capacitance increased with increasing Pt concentration in the composite layer and optimal values as high as 4.3 ± 1.3 kF/m at 50 vol % Pt were recorded. The specific electrode surface area calculated from this data was in good agreement with the data obtained from image analysis. © 2001 American Institute of Physics.

Bibliographic Details

M. G. H. M. Hendriks; M. J. G. W. Heijman; W. E. van Zyl; J. E. ten Elshof; H. Verweij

AIP Publishing

Physics and Astronomy

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know