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Calorimetric study of plastically crystalline o- and m-carboranes

Journal of Chemical Physics, ISSN: 0021-9606, Vol: 119, Issue: 9, Page: 4775-4781
2003
  • 19
    Citations
  • 0
    Usage
  • 10
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    19
    • Citation Indexes
      19
  • Captures
    10

Article Description

An m-carborane undergoes two phase transitions at 284 K and 170 K and is likely to be ordered at 0 K. As such, o-carborane exhibited two phase transitions at 275 K and 160 K. A glass transition occurs at 120 K in the low-temperature phase. This glass transition is due tot eh freezing of molecular reorientation.

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