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Diffusion-diffusion correlation and exchange as a signature for local order and dynamics

Journal of Chemical Physics, ISSN: 0021-9606, Vol: 120, Issue: 8, Page: 4032-4038
2004
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Article Description

The use of new two-dimensional nuclear magnetic resonance experiment in the examination of local diffusional anisotropy under conditions of global isotropy was demonstrated. The measurement of diffusional anisotropy for water molecules in a polydomain lamellar phase lytropic liquid crystal, 40 wt% nonionic surfactant CE(CH O(CHCH O)H) in HO was also presented. The diffusion-diffusion correlation spectroscopy and diffusion exchange spectroscopy employ successive pairs of magnetic field gradient pulses, with signal analysis using two-dimensional inverse Laplace transformation.

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