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The growth and optical properties of large, high-quality AlN single crystals

Journal of Applied Physics, ISSN: 0021-8979, Vol: 96, Issue: 10, Page: 5870-5876
2004
  • 104
    Citations
  • 0
    Usage
  • 78
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    104
    • Citation Indexes
      103
    • Patent Family Citations
      1
      • 1
  • Captures
    78

Article Description

The effect of impurities and defects on the optical properties of AlN was investigated. High-quality A1N single crystals of more than 20 mm size were examined. Different crucible materials and growth procedures were applied to the growth of bulk A1N by physical vapor transport method to vary the defect and the impurity concentrations. The crystalline orientation was investigated by Raman spectroscopy. Glow discharge mass spectrometry was used to determine the trace concentration of the incorporated impurities such as oxygen and carbon. The photoluminescence emission and absorption properties of the crystals revealed bands around 3.5 and 4.3 eV at room temperature. Absorption edges ranging between 4.1 and 5.95 eV were observed. Since no straight correlation of the oxygen concentration was obtained, a major contribution of oxygen or oxygen-related impurities was ruled out to generate the observed emission and absorption bands in the Ultraviolet spectral range. The carbon-related impurities and intrinsic defects might contribute to the observed optical properties. The absorption coefficient for A1N single crystals has been derived for the spectral range below the band edge. © 2004 American Institute of Physics.

Bibliographic Details

Martin Strassburg; Jayantha Senawiratne; Nikolaus Dietz; Ute Haboeck; Axel Hoffmann; Vladimir Noveski; Rafael Dalmau; Raoul Schlesser; Zlatko Sitar

AIP Publishing

Physics and Astronomy

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