Projected dynamics: Analysis of a chemical reaction model
The Journal of Chemical Physics, ISSN: 0021-9606, Vol: 91, Issue: 9, Page: 5528-5543
1989
- 17Citations
- 6Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Article Description
The rate processes corresponding to barrier crossing dynamics in a symmetric double-well potential driven by a white-noise source are investigated. The rate kernels in the generalized phenomenological rate law describing the reaction involve time evolution through a projected Fokker-Planck operator. The spectral properties of the projected Fokker-Planck operator are studied, and the rate kernels are expressed in terms of the eigenvalues and eigenfunctions of this operator. The formal results are illustrated with numerical calculations. The results provide information on the nature of the generalized chemical rate law for fast processes. © 1989 American Institute of Physics.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=2942556420&origin=inward; http://dx.doi.org/10.1063/1.457556; https://pubs.aip.org/jcp/article/91/9/5528/93057/Projected-dynamics-Analysis-of-a-chemical-reaction; http://aip.scitation.org/doi/10.1063/1.457556; https://aip.scitation.org/action/captchaChallenge?redirectUrl=https%3A%2F%2Faip.scitation.org%2Fdoi%2F10.1063%2F1.457556
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