Vibrational structure in atomic emission spectra: Hg atoms in molecular matrices
Journal of Chemical Physics, ISSN: 0021-9606, Vol: 107, Issue: 7, Page: 2205-2214
1997
- 8Citations
- 3Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Mercury atoms excited to the P state in rare gas and molecular (CH, CD, CF, and SF) matrices relax by a direct P→S fluorescence with a ca. 60 ns lifetime or by the P-/\/\/\>P radiationless transition followed by the P→S long-lived (τ in the 10 to 500 ms range) emission. The main difference between atomic and molecular hosts is the appearance, in the latter case, of a well resolved vibrational structure in the spectrum of the P→S transition involving the frequencies of nontotally symmetric modes of the host molecules. This structure, related to a shortening of the lifetime of the P→S emission is explained by the intensity borrowing from the allowed P→S transition, i.e., by the P↔P mixing induced by nontotally symmetric vibrations of neighbor molecules (analog of the Herzberg-Teller effect). Relative intensities of bands corresponding to different vibrational modes may be deduced from estimation of electric fields induced in the Hg atom by displacements of electric charges of the vibrating molecule © 1997 American Institute of Physics.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0242678711&origin=inward; http://dx.doi.org/10.1063/1.474600; https://pubs.aip.org/jcp/article/107/7/2205/183105/Vibrational-structure-in-atomic-emission-spectra; http://aip.scitation.org/doi/10.1063/1.474600; https://aip.scitation.org/action/captchaChallenge?redirectUrl=https%3A%2F%2Faip.scitation.org%2Fdoi%2F10.1063%2F1.474600
AIP Publishing
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know