Synchrotron far infrared spectroscopy of the ground, ν , and ν states of thiirane
Journal of Chemical Physics, ISSN: 0021-9606, Vol: 137, Issue: 8, Page: 084306
2012
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Article Description
The high-resolution (0.001 cm ) spectrum of thiirane has been recorded at the far-infrared beamline at the Australian synchrotron between 760400 cm and 17010 cm . Ro-vibrational transitions of the highly Coriolis coupled ν (628.1 cm ) and ν (669.7 cm ) fundamentals, as well as pure rotational far-IR transitions have been assigned, and rotational, centrifugal distortion, and Coriolis interaction parameters determined. ν gains the vast majority of its intensity from an interesting Coriolis intensity stealing mechanism, which is also outlined. © 2012 American Institute of Physics.
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AIP Publishing
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