Laser spectroscopy and crystal field analysis of Cm diluted in CsNaYCl
Journal of Chemical Physics, ISSN: 0021-9606, Vol: 108, Issue: 15, Page: 6353-6361
1998
- 21Citations
- 9Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Laser selective excitation, excited state absorption, two-photon absorption, and fluorescence line narrowing techniques have been used to investigate the electronic energy level structure of the Cm ion diluted in the host crystal CsNaYCl. In this crystal the Cm ion replaces a Y ion at an octahedral site (O symmetry). Analysis of these spectra resulted in the assignment of 52 energy levels, which were fitted to the parameters of an empirical Hamiltonian with a rms deviation of 57 cm. Many of the Γ symmetry levels exhibited small splittings, which was indicative of a site symmetry lower than O. The energies of the most prominent vibronic features have been measured and assigned to specific vibrational modes of the CmCl moiety or to lattice modes. The lifetimes of four fluorescing levels have been obtained at room and liquid helium temperatures. These were analyzed to determine the processes which contribute to the relaxation of an excited Cm ion in this host. Blue P→S upconversion fluorescence was observed when pumping the orange S→D absorption transitions and explained by a phonon-assisted energy transfer mechanism. © 1998 American Institute of Physics.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0001650930&origin=inward; http://dx.doi.org/10.1063/1.476042; https://pubs.aip.org/jcp/article/108/15/6353/477336/Laser-spectroscopy-and-crystal-field-analysis-of; http://aip.scitation.org/doi/10.1063/1.476042; https://aip.scitation.org/action/captchaChallenge?redirectUrl=https%3A%2F%2Faip.scitation.org%2Fdoi%2F10.1063%2F1.476042
AIP Publishing
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know