Solving the Poisson-Boltzmann equation to obtain interaction energies between confined, like-charged cylinders
Journal of Chemical Physics, ISSN: 0021-9606, Vol: 109, Issue: 20, Page: 9166-9171
1998
- 38Citations
- 22Captures
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Article Description
We numerically solve the nonlinear Poisson-Boltzmann equation for two cylinders confined by two parallel charged plates. The repulsive electrical double layer component of the cylinder pair potential is substantially reduced by confinement between like-charged plates. While the effective cylinder surface charge is increased by the confinement, the effective interaction screening length is reduced, this effect being dominant so that the repulsive confined cylinder-cylinder interaction potential is reduced. © 1998 American Institute of Physics.
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