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Nonadditive intermolecular potential and thermodynamic properties of ethane

Journal of Chemical Physics, ISSN: 0021-9606, Vol: 113, Issue: 1, Page: 312-319
2000
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Article Description

Ab initio calculations of the pair interaction energy were carried out. By including nonadditive interactions, a clearly identified component of the interaction potential representing pairwise properties was retained. Further, the nonadditive contribution was transformed into a temperature and density-dependent pairwise effect term.

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