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Photoelectron spectroscopy of boron aluminum hydride cluster anions

Journal of Chemical Physics, ISSN: 0021-9606, Vol: 140, Issue: 16, Page: 164317
2014
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Boron aluminum hydride clusters are studied through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations. Boron aluminum hydride cluster anions, BAl H, were generated in a pulsed arc cluster ionization source and identified by time-of-flight mass spectrometry. After mass selection, their photoelectron spectra were measured by a magnetic bottle-type electron energy analyzer. The resultant photoelectron spectra as well as calculations on a selected series of stoichiometries reveal significant geometrical changes upon substitution of aluminum atoms by boron atoms. © 2014 AIP Publishing LLC.

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