Novel optoelectronic technique for direct tracking of ultrafast triplet excitons in polymeric semiconductor

The exciton physics of organic semiconductors is exotic. It is a domain in which singlet and triplet kinetics both play an important role in determining the performance of various optoelectronic devices. Since triplet excitons are non-emissive, it brings further challenges in the understanding of triplet kinetics. In this work, we have studied the effect of polymer chain packing on triplet diffusion in the polyfluorene based polymeric system, which is known to give efficient organic light emitting diode (OLED) efficiency for display devices. Furthermore, this polyfluorene system exhibits an efficient triplet-triplet fusion process, which provides singlet excitons as delayed fluorescence and becomes a tool to study triplet exciton kinetics. We have developed a unique method to trace the position of the triplet exciton in the emissive layer of OLEDs by analyzing angle-resolved delayed electroluminescence emission patterns as a function of time. This study could provide exciton transport kinetics in the transverse direction from the substrate plane. Furthermore, direct visualization of the delayed photoluminescence imaging technique could provide lateral transport kinetics of triplet excitons. Results suggest that the diffusion is significantly anisotropic in thinner films. As the thickness of the film increases, anisotropy reduces in triplet transport. Moreover, we noticed that in thicker polymeric semiconductor films, diffusivity approaches close to ultrahigh 10 cm s, which is similar to the values that are reported for acene-based molecular crystalline thin films. Our results also provide important insight into efficient electroluminescence in unusually thick (1.2 μm) polyfluorene-based emissive layers of OLEDs.