Structural characterization of novel ionic salts incorporating trihalide anions
Australian Journal of Chemistry, ISSN: 0004-9425, Vol: 62, Issue: 4, Page: 334-340
2009
- 22Citations
- 25Captures
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Article Description
The crystal structures of several low-melting salts containing trihalide ions, namely 1-ethyl-3-methylimidazolium tribromide ([Cmim][Br ]), 1-ethyl-1-methylpyrrolidinium tribromide ([Cmpyr] [Br]), and 1-propyl-1-methylpyrrolidinium triiodide ([C mpyr][I]), are reported for the first time. Thermal analysis reveals that the tribromide salts are lower-melting than their monohalide analogues. Analysis of the crystal structures allows examination of the influence of the anions on the physical properties of the salts. © 2009 CSIRO.
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