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Mg, Ca, and Co metal-organic framework materials with [Si(p-CHCO) (p-CHCOH)] struts

Australian Journal of Chemistry, ISSN: 0004-9425, Vol: 64, Issue: 9, Page: 1237-1244
2011
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Conference Paper Description

Three new metal-organic framework materials [Mg(LH) (EtOH)(HO)]·(EtOH) (HO) (IMP-13Mg), [Co (LH)(EtOH)(HO)]·(EtOH) (IMP-13Co), and [Ca(LH)(EtOH) ]·(EtOH) (IMP-14) have been prepared from the treatment of silanetetrabenzoic acid (L-H) with Mg, Co, and Ca salts respectively. In all cases the silanetetrabenzoic acid has been triply deprotonated and the resultant carboxylate groups assemble with trinuclear metal-based nodes to give (3,6)-connected kgd-type two-dimensional layers. These layers are then extended into the third dimension by coordination of the metal nodes by carboxylic acid groups in adjacent layers. In the case of IMP-13Mg/Co, only alternate L-H connectors and metal nodes are involved in these interlayer interactions, leaving some acid groups free within the structure. However, in IMP-14 all L-H connectors and metal nodes participate in interlayer bonding. © 2011 CSIRO.

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