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Should the asymmetry of enzymatic active centers always correlate with the asymmetry of their substrates?

Journal of Biomolecular Structure and Dynamics, ISSN: 1538-0254, Vol: 14, Issue: 2, Page: 225-230
1996
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Article Description

Analysis of the substrate specificity of DNA polymerases and in part some other enzymes of nucleic acid metabolism towards unnatural L-stereomeric nucleosides and nucleotides was made. As a result, the hypothesis is proposed that when the chiral part of the substrate molecule does not interact specifically with the enzyme, substitution of natural D enantiomers by L compounds is possible. © 1996 Taylor & Francis Group, LLC.

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