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Detecting enthalpy ‘cross-over’ in vitrified solids by differential scanning calorimetry

Philosophical Magazine Letters, ISSN: 1362-3036, Vol: 64, Issue: 1, Page: 37-43
1991
  • 24
    Citations
  • 0
    Usage
  • 6
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    24
    • Citation Indexes
      24
  • Captures
    6

Article Description

It is proposed that the ‘cross-over’ of enthalpy associated with the structural relaxation of a vitreous solid can be conveniently studied by differential scanning calorimetry using thermal scans. Observations on a network structure (0.4 NaO, 0.1 CaO, 0.05 AlO0.05 SiO0.4 PO), a linear-chain polymer (poly methyl methacrylate) and a nonpolar rigid molecule (1, 3, 5-tri-α-naphthylbenzene) glass illustrate the usefulness of the method for routinely studying this aspect of structural relaxation. © 1991 Taylor & Francis Group, LLC.

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