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Phosphorylation of allyl halides with white phosphorus

Phosphorus, Sulfur and Silicon and the Related Elements, ISSN: 1042-6507, Vol: 178, Issue: 3, Page: 425-429
2003
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Article Description

White phosphorus reacts with allyl bromide in the system KOH-dioxane-HO at room temperature to form tris(propen-2-yl), bis(propen-2-yl)(E-propen-1-yl), and bis(E-propen-1-yl)(propen-2-yl)phosphine oxides in a total quantitative yield, their molar ratio being 1:0.5:0.1.

Bibliographic Details

Svetlana Malysheva; Boris Sukhov; Nina Gusarova; Svetlana Shaikhudinova; Tat'yana Kazantseva; Natal'ya Belogorlova; Vladimir Kuimov; Boris Trofimov

Informa UK Limited

Biochemistry, Genetics and Molecular Biology; Chemistry

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