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The syntheses of 2-hydroxybenzothiazole substituted cyclotriphosphazenes: Spectroscopic characterizations

Phosphorus, Sulfur and Silicon and the Related Elements, ISSN: 1563-5325, Vol: 199, Issue: 4, Page: 277-282
2024
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Article Description

The nucleophilic substitution reactions of mono- and bis-spiro-2,2’-dioxybiphenyl cyclotriphosphazenes (1a and 1b) with 2-hydroxybenzothiazole (2) were performed in the presence of metallic sodium in THF. Two novel 2-oxybenzothiazole-substituted spiro-2,2′-dioxybiphenyl cyclotriphosphazene derivatives (3a and 3b) were obtained from these reactions. Both compounds (3a, 3b) have been characterized by elemental analysis as well as by H, C and P NMR spectroscopy. Compounds 3a and 3b are reported for the first time in this study.

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